Devon Walter Meek Lecture

Image
Tim Barckholtz
November 8, 2019
2:30PM - 3:30PM
Location
Various Locations

Date Range
Add to Calendar 2019-11-08 14:30:00 2019-11-08 15:30:00 Devon Walter Meek Lecture

Tim Barckholtz, ExxonMobil

Tim received a B.S. degree in chemistry and math from Trinity University (San Antonio), and received a Ph.D. in chemistry with co-advisors, Profs. Terry Miller (physical chemistry) and Bruce Bursten (inorganic chemistry) from The Ohio State University. Following a post-doctoral appointment at NIST and the University of Colorado, he joined ExxonMobil’s Corporate Strategic Research Labs in 2001. He has held a number of positions in research, crude oil supply chain management, and research management. His current R&D activities are focused on novel methods for CO2 capture using carbonate fuel cells and other emerging technologies. He currently holds the position of Senior Scientific Advisor.

Explorations at the Intersection of Energy and the Environment
Thursday, November 7
CBEC 130
2:30pm to 3:30pm 

The world is facing a daunting challenge: how to provide the energy an increasing population needs, yet do so in an environmentally responsible way. This talk will summarize three different projects that have each, in very different ways, tackled this problem:

  • Modeling the chemical kinetics of internal combustion engines to identify new approaches for increasing efficiency
  • Developing new technology to reduce the NOx emissions from fluidized catalytic crackers in refineries
  • Creating a new concept in CO2 capture from combustion flue gas

Sadly, none of these projects involved metal-metal bonds or the Jahn-Teller effect. However, the talk will include a discussion of how the skills and thought processes accumulated in the mid-1990s working on those topics were put to good use on these industrial problems.

Undergraduate Poster Session
5:30 to 7:00pm in CBEC Lobby

CO2 Capture Using Carbonate Fuel Cells
Friday, November 8
Evans 1008
12:40pm to 1:40pm

Power generation facilities account for a large share of global CO2 emissions and are also some of the largest point sources, with a typical facility emitting several million tons annually. Thus, they are an obvious target for CO2 capture. Carbon capture from coal-fired power generation has been the subject of considerable research and several world-scale projects, while capture from natural gas combined cycle (NGCC) power generation has been much less investigated, despite NGCC generation having approximately half of the CO2 emissions than coal power generation.

In this talk, I will describe how carbonate fuel cells can be used for CO2 capture from NGCC facilities without a significant energy debit. The exhaust from the NGCC system is taken as the inlet to the cathode of the fuel cell, with additional natural gas and steam fed to the anode. Within the fuel cell, the natural gas is reformed to hydrogen in the anode, while the CO2 is combined with oxygen and electrons from the power circuit to make the carbonate ion. The carbonate ion is then transferred through the membrane of the fuel cell to the anode, where the ions react with hydrogen to produce CO2 and H2O, and high potential electrons for the power circuit. In this process, additional power is created by the fuel cells, keeping the total efficiency of the system at or near the efficiency of the NGCC system without CO2 capture.

This presentation will summarize the current status of this technology. We have obtained substantial proof-of-principle data at the benchtop scale, using single cells of about 50 – 100 W power each. We also have obtained data using a 30 kW fuel cell stack, which is nearly full size in length and width, just limited in height and number of cells. We have also demonstrated the production of large volumes of hydrogen as a valuable co-product. All of this data indicates the technology is feasible and promising.

The Devon Walter Meek Lectures

devon_walter_meek_headshot
                    Devon Walter Meek

The Devon Walter Meek was born in Kentucky in 1936. He earned his bachelor's degree from Berea College in Kentucky in 1958, and master's and doctoral degrees in chemistry from the University of Illinois in 1960 and 1961, respectively. He joined the faculty of the Chemistry Department at The Ohio State University in 1961. After 27 years of dedicated service, Professor Meek retired on November 1, 1988, having also served as Chairman of the Department of Chemistry from 1977 to 1981 and from 1986 until his retirement. Dr. Meek passed away on December 7, 1988, at age 52.

Dr. Meek's research included studies of transition metal complexes, homogeneous catalysis and activation as well as stabilization of small molecules by transition metal complexes of polyphosphine ligands.

The Devon W. Meek Industrial Lectureship began in 1989. Faculty of the Chemistry Department choose a distinguished chemist who has impacted industry, who gives two lectures, one typically on a scientific topic of current social relevance. Also, as part of the Meek Lecture, undergraduate researchers in the Chemistry Department present their research to the faculty, staff, students and invited guests.

This Lectureship is designed to be an ongoing tribute to Dr. Meek's distinguished career of research, teaching, and service. It especially recognizes his untiring efforts to establish industrial/academic ties and to encourage students to pursue careers in chemistry.

 

Previous Lecturers:

2018- Peter Kim

2017- Dennis Liotta

2016 - Jim McGuire

2014 - Jay Keasling

2013 - Ray Goodrich

2012 - James Stevens

2011 - John Kozarich

2010 - Mark Hampden-Smith

2009 - William Nugent

2008 - Jeffrey Bricker

2007 - Allison Campbell

2006 - Duane Burnett

2005 - Carl F. Kohrt

List of Previous Lectures back to 1989.pdf

 
Various Locations Department of Chemistry and Biochemistry chem-biochem@osu.edu America/New_York public
Description

Tim Barckholtz, ExxonMobil

Tim received a B.S. degree in chemistry and math from Trinity University (San Antonio), and received a Ph.D. in chemistry with co-advisors, Profs. Terry Miller (physical chemistry) and Bruce Bursten (inorganic chemistry) from The Ohio State University. Following a post-doctoral appointment at NIST and the University of Colorado, he joined ExxonMobil’s Corporate Strategic Research Labs in 2001. He has held a number of positions in research, crude oil supply chain management, and research management. His current R&D activities are focused on novel methods for CO2 capture using carbonate fuel cells and other emerging technologies. He currently holds the position of Senior Scientific Advisor.

Explorations at the Intersection of Energy and the Environment
Thursday, November 7
CBEC 130
2:30pm to 3:30pm 

The world is facing a daunting challenge: how to provide the energy an increasing population needs, yet do so in an environmentally responsible way. This talk will summarize three different projects that have each, in very different ways, tackled this problem:

  • Modeling the chemical kinetics of internal combustion engines to identify new approaches for increasing efficiency
  • Developing new technology to reduce the NOx emissions from fluidized catalytic crackers in refineries
  • Creating a new concept in CO2 capture from combustion flue gas

Sadly, none of these projects involved metal-metal bonds or the Jahn-Teller effect. However, the talk will include a discussion of how the skills and thought processes accumulated in the mid-1990s working on those topics were put to good use on these industrial problems.

Undergraduate Poster Session
5:30 to 7:00pm in CBEC Lobby

CO2 Capture Using Carbonate Fuel Cells
Friday, November 8
Evans 1008
12:40pm to 1:40pm

Power generation facilities account for a large share of global CO2 emissions and are also some of the largest point sources, with a typical facility emitting several million tons annually. Thus, they are an obvious target for CO2 capture. Carbon capture from coal-fired power generation has been the subject of considerable research and several world-scale projects, while capture from natural gas combined cycle (NGCC) power generation has been much less investigated, despite NGCC generation having approximately half of the CO2 emissions than coal power generation.

In this talk, I will describe how carbonate fuel cells can be used for CO2 capture from NGCC facilities without a significant energy debit. The exhaust from the NGCC system is taken as the inlet to the cathode of the fuel cell, with additional natural gas and steam fed to the anode. Within the fuel cell, the natural gas is reformed to hydrogen in the anode, while the CO2 is combined with oxygen and electrons from the power circuit to make the carbonate ion. The carbonate ion is then transferred through the membrane of the fuel cell to the anode, where the ions react with hydrogen to produce CO2 and H2O, and high potential electrons for the power circuit. In this process, additional power is created by the fuel cells, keeping the total efficiency of the system at or near the efficiency of the NGCC system without CO2 capture.

This presentation will summarize the current status of this technology. We have obtained substantial proof-of-principle data at the benchtop scale, using single cells of about 50 – 100 W power each. We also have obtained data using a 30 kW fuel cell stack, which is nearly full size in length and width, just limited in height and number of cells. We have also demonstrated the production of large volumes of hydrogen as a valuable co-product. All of this data indicates the technology is feasible and promising.

The Devon Walter Meek Lectures

devon_walter_meek_headshot
                    Devon Walter Meek

The Devon Walter Meek was born in Kentucky in 1936. He earned his bachelor's degree from Berea College in Kentucky in 1958, and master's and doctoral degrees in chemistry from the University of Illinois in 1960 and 1961, respectively. He joined the faculty of the Chemistry Department at The Ohio State University in 1961. After 27 years of dedicated service, Professor Meek retired on November 1, 1988, having also served as Chairman of the Department of Chemistry from 1977 to 1981 and from 1986 until his retirement. Dr. Meek passed away on December 7, 1988, at age 52.

Dr. Meek's research included studies of transition metal complexes, homogeneous catalysis and activation as well as stabilization of small molecules by transition metal complexes of polyphosphine ligands.

The Devon W. Meek Industrial Lectureship began in 1989. Faculty of the Chemistry Department choose a distinguished chemist who has impacted industry, who gives two lectures, one typically on a scientific topic of current social relevance. Also, as part of the Meek Lecture, undergraduate researchers in the Chemistry Department present their research to the faculty, staff, students and invited guests.

This Lectureship is designed to be an ongoing tribute to Dr. Meek's distinguished career of research, teaching, and service. It especially recognizes his untiring efforts to establish industrial/academic ties and to encourage students to pursue careers in chemistry.

 

Previous Lecturers:

2018- Peter Kim

2017- Dennis Liotta

2016 - Jim McGuire

2014 - Jay Keasling

2013 - Ray Goodrich

2012 - James Stevens

2011 - John Kozarich

2010 - Mark Hampden-Smith

2009 - William Nugent

2008 - Jeffrey Bricker

2007 - Allison Campbell

2006 - Duane Burnett

2005 - Carl F. Kohrt

List of Previous Lectures back to 1989.pdf

 

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